Here are two guides for power source diagnostics and general power source information:
[url]http://www.fonerbooks.com/power.htm[/url]
[url]http://www.quepublishing.com/articles/article.asp?p=31105&seqNum=4[/url]
It's easy to check if the p.s. works, just create a connection between pin 4 and pin 14 (there are 5 volts going through here but be careful anyways, using a cable with bioth ends 'shaved' is a good option) that should make the p.s. get started, you'll notice the fan spinning.
[img]http://www.quepublishing.com/content/images/chap3_078972927X/elementLinks/03fig08.jpg[/img]
You should have a similar diagram on your p.s. check for the PS_ON pins, 4 and 14.